ETHYLENEDIAMINE

UN Number: 1604 - CAS Number: 107-15-3

Also known as: 1,2-DIAMINOETHANE, DIMETHYLENEDIAMINE, Ethane-1,2-Diamine, 1,2-Ethanediamine, Ethylenediamine
Information on chemical

Information on chemical

External resources

CAMEO Chemical Database
WISER Substance List

Description

UN number 1604
CAS number 107-15-3
Formula C2H8N2

Physical chemical data

Physical State (20°C) Liquid
Physical State (25°C) Liquid
Density (kg/m3)
909 [Kg/m³] at a temperature of 20°C
Kinematic viscosity (cSt)
0.017151 [cSt] at a temperature of 25°C
Molar mass (g/mol) 60.1
Density of gas (kg/m3) 2.709
Solubility (g/L)
110000 [g/L] at a temperature of 20°C and salinity of 0‰
Boiling Point (°C) 117
Melting Point (°C) 11.14
Critical temperature (°C) 613.1
Critical pressure (Pa) 6710000
Vapour Pressure (Pa)
1200 [Pa] at a temperature of 20°C
Ignition Temperature (°C) 385
Flash Point (°C) 34
Flash Point (Pensky-Martens closed cup) (°C) 34
Lower explosivity limit (LEL) (volume %) 5.8
Upper explosivity limit (UEL) (volume %) 11.1
Vapor enthalpy (J/Kg)
631968 [J/Kg] at a temperature of 117°C
748444 [J/Kg] at a temperature of 25°C
Specific heat capacity (J/(Kg·K)) 2872
Henry's constant (mol/(m³·Pa)) 0.00018

Behaviour at sea

Log kow -1.3
Log koc 1.17
Bioconcentration factor (BCF) 1

Additional data

Colour colourless
Odour mild ammonia odour
MARPOL pollution category
Category Description
Y Noxious Liquid Substances which, if discharged into the sea from tank cleaning or deballasting operations, are deemed to present a hazard to either marine resources or human health or cause harm to amenities or other legitimate uses of the sea and therefore justify a limitation on the quality and quantity of the discharge into the marine environment.

Transportation data

Transport mode Bulk,Packaged
Package group II
State liquid
Temperature (°C) ambient
Pressure (Pa) under pressure
Family name aliphatic amines

Reactivity data

Water Yes
Abilities Miscible in water.
Acid(s) Yes
Base(s) No
Metal(s) and alloys No
Oxidizing agents Yes
Reducing agents No
Combustibles No
Organic substance Yes

GESAMP Hazard profile

Bioaccumulation in logPow (A1A) 0 - e <1, or > ca.7, or Mol. Wt. > 1000
Bioaccumulation in BCF (A1B) 1 - ≥1 and <10
Bioaccumulation (A1) 1 - Very low potential to bioaccumulate
Biodegradation (A2) R - Readily biodegradable
Acute aquatic toxicity (B1) (LC/EC/IC50 (mg/l)) 3 - Moderately toxic
Chronic aquatic toxicity (B2) (NOEC (mg/l)) 1 - Low
Acute mammalian toxicity by swallowing (C1) (LD50 (mg/kg)) 1 - Slight
Acute mammalian toxicity by skin penetration (C2) (LD50 (mg/kg)) 2 - Moderate
Acute mammalian toxicity by inhalation (C3) (LC50 (mg/l)) 1 - Slight
Skin irritation/corrosivity (D1) 1 - Mildly irritating
Eye irritation/corrosivity (D2) 3 - Severely irritating, with irreversible corneal injury
Interference with coastal amenities (E2) D - Dissolver
Effects on wildlife and bottom habitats (E3) 3 - Is highly acutely toxic; and/or is severely irritant or corrosive to skin or eyes; and/or is carcinogenic, mutagenic or reprotoxic; and/or is a floater or persistent floater with associated health effects

Human toxicity threshold

Corrosive Flammable Flammable liquid Health Hazard Toxic
IDHL 2000
Hazard statements
Physical
H226 Flammable liquid and vapour.
Health
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Environmental
H412 Harmful to aquatic life with long lasting effects.
Precautionary statements
General
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
Prevention
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/attention.
Storage
P405 Store locked up.
Disposal
P501 Dispose of contents/container to ...
TLV-TWA 10
10 min 30 min 60 min 4 hrs 8 hrs
AEGL-2 (ppm) 12 12 9.7 6.1 4.8
AEGL-3 (ppm) 25 25 20 13 10

Ecotoxicity

Lowest median lethal concentration (LC50) on algae (mg/l) 61
Lowest median lethal concentration (LC50) on crustacean (mg/l) 3
Lowest median lethal concentration (LC50) on fishes (mg/l) 115.7
Highest no observed effect concentration (NOEC) on crustacean (mg/l) 0.16
Highest no observed effect concentration (NOEC) on fishes (mg/l) > 10
Assessment factor (AF)
100 on the Short term
Predicted No Effect Concentration (PNEC) (µg/l)
2 [µg/l] on the Short term
Incident reports

Incident reports

No incident reports available

Emergency Response Guidebook

Emergency Response Guidebook

Guide number: 132

See the guide or download the emergency response guidebook

At sea emergency guide

At sea emergency guide

Emergency schedule: 8-04

CORROSIVE SUBSTANCES, FLAMMABLE, FLASHPOINT 61°C Closed Cup OR BELOW.

Emergency procedures

Action

Avoid all sources of ignition (e.g. naked lights, unprotected light bulbs, electric handtools).

Spillage on deck

Wash overboard with copious quantities of water.

Spillage under deck

Collect spillage, where practicable, using absorbent material for liquids, for safe disposal.

Fire on deck

Use water spray.

Fire under deck

Batten down; use ship's fixed fire-fighting installation. Otherwise adopt action as for "On deck".

Special equipment to be carried

Protective clothing (gloves, boots, coveralls, headgear).
Self-contained breathing apparatus.
Spray nozzles.

Decision trees

Decision trees

No decision trees available

No additional data

last modified 2020-12-14T09:02:28+00:00