HYDROGEN PEROXIDE solutions (8 to 60%)

UN Number: 2014 - CAS Number: 7722-84-1

Also known as: EAU OXYGENEE, Hydroperoxide, Hydrogen Peroxide, Peroxyde D'Hydrogene
Information on chemical

Information on chemical

External resources

CAMEO Chemical Database
WISER Substance List

Description

UN number 2014
CAS number 7722-84-1
Formula H2O2

Physical chemical data

Physical State (20°C) Liquid
Physical State (25°C) Liquid
Density (kg/m3)
1000/1200 [Kg/m³] at a temperature of 20°C
Molar mass (g/mol) 34.01 (pure)
Density of gas (kg/m3) 1.29/1.55
Solubility (g/L)
10000000 [g/L] at a temperature of 20°C and salinity of 0‰
Boiling Point (°C) 100/114
Melting Point (°C) -50
Critical temperature (°C) 728
Critical pressure (Pa) 22000000
Surface tension (mN/m)
80.4 [mN/m] at a temperature of 20°C
Vapour Pressure (Pa)
40/100 [Pa] at a temperature of 20°C
262.6 [Pa] at a temperature of 25°C
Vapor enthalpy (J/Kg)
1517000 [J/Kg] at a temperature of 25°C
Specific heat capacity (J/(Kg·K)) 2619
Henry's constant (mol/(m³·Pa)) 0.0007

Behaviour at sea

Log kow -1.57
Log koc 1.12

Additional data

Colour colourless
Odour slighty sharp
MARPOL pollution category
Category Description
Y Noxious Liquid Substances which, if discharged into the sea from tank cleaning or deballasting operations, are deemed to present a hazard to either marine resources or human health or cause harm to amenities or other legitimate uses of the sea and therefore justify a limitation on the quality and quantity of the discharge into the marine environment.

Transportation data

Transport mode Bulk,Packaged
Package group I/II
State liquid
Temperature (°C) ambient
IMO class 5.1

Reactivity data

Water No
Abilities Miscible in water.
Acid(s) Yes
Base(s) Yes
Metal(s) and alloys Yes
Oxidizing agents Yes
Reducing agents Yes
Combustibles Yes
Organic substance Yes

GESAMP Hazard profile

Bioaccumulation in BCF (A1B) 0 - No measurable BCF
Bioaccumulation (A1) 0 - No potential to bioaccumulate
Acute aquatic toxicity (B1) (LC/EC/IC50 (mg/l)) 3 - Moderately toxic
Acute mammalian toxicity by swallowing (C1) (LD50 (mg/kg)) 1 - Slight
Acute mammalian toxicity by skin penetration (C2) (LD50 (mg/kg)) 0 - Negligible
Acute mammalian toxicity by inhalation (C3) (LC50 (mg/l)) 2 - Moderate
Skin irritation/corrosivity (D1) 1 - Mildly irritating
Eye irritation/corrosivity (D2) 3 - Severely irritating, with irreversible corneal injury
Interference with coastal amenities (E2) D - Dissolver
Effects on wildlife and bottom habitats (E3) 3 - Is highly acutely toxic; and/or is severely irritant or corrosive to skin or eyes; and/or is carcinogenic, mutagenic or reprotoxic; and/or is a floater or persistent floater with associated health effects

Human toxicity threshold

Corrosive Harmful Oxidizing
IDHL 75
Hazard statements
Physical
H271 May cause fire or explosion, strong oxidiser.
Health
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
Environmental
H412 Harmful to aquatic life with long lasting effects.
Precautionary statements
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P370 + P378 In case of fire: Use ... for extinction.
ERPG-1 (ppm) 10
ERPG-2 (ppm) 50
ERPG-3 (ppm) 100

Ecotoxicity

Lowest median lethal concentration (LC50) on crustacean (mg/l) 2.4
Lowest median lethal concentration (LC50) on fishes (mg/l) 0.1
Highest no observed effect concentration (NOEC) on algae (mg/l) 0.1
Highest no observed effect concentration (NOEC) on crustacean (mg/l) 0.61
Highest no observed effect concentration (NOEC) on fishes (mg/l) 5
Assessment factor (AF)
50 on the Short term
Predicted No Effect Concentration (PNEC) (µg/l)
10 [µg/l] on the Short term
Incident reports

Incident reports

Year Vessel Location Cargo type
1984 Barge Fly River Estuary, Papua New Guinea Package
Emergency Response Guidebook

Emergency Response Guidebook

Guide number: 140

See the guide or download the emergency response guidebook

At sea emergency guide

At sea emergency guide

Emergency schedule: 5.1-02

LIQUID OXIDIZING SUBSTANCES, TOXIC AND/OR CORROSIVE.

Emergency procedures

Action

Turn ship off-wind.

Spillage on deck

Wash spillage overboard with copious quantities of water from as far away as practicable. Contaminated clothing must be removed and washed carefully with copious quantities of water.

Spillage under deck

Collect spillage, where practicable, using inert absorbent materials, for safe disposal. Do not use sawdust or other combustible materials as absorbents. Contaminated clothing must be removed and washed carefully with copious quantities of water.

Fire on deck

Use copious quantities of water from as far away as practicable.

Fire under deck

Ship's fixed fire-fighting installation may not be effective. Adopt action as for "On deck".

Special equipment to be carried

Protective clothing (gloves, boots, coveralls, headgear).
Self-contained breathing apparatus.
Inert absorbent material (e.g. diatomaceous earth).

Remarks by UN no.

• TETRANITROMETHANE (UN No. 1510).
May explode in a fire situation.

• HYDROGEN PEROXIDE, AQUEOUS SOLUTIONS (UN No. 2984), with not less
than 8% but less than 20% hydrogen peroxide.
Self-contained breathing apparatus not necessary - use goggles for eye protection.

Decision trees

Decision trees

No decision trees available

No additional data

last modified 2020-12-14T09:02:35+00:00