VINYLIDENE CHLORIDE inhibited

UN Number: 1303 - CAS Number: 75-35-4

Also known as: CHLORURE DE VINYLIDENE
Information on chemical

Information on chemical

External resources

CAMEO Chemical Database
WISER Substance List

Description

UN number 1303
CAS number 75-35-4

Physical chemical data

Physical State (20°C) Liquid
Density (kg/m3)
1210 [Kg/m³] at a temperature of 20°C
Molar mass (g/mol) 96.95
Density of gas (kg/m3) 4.322
Boiling Point (°C) 31.8
Melting Point (°C) -122
Vapour Pressure (Pa)
66500 [Pa] at a temperature of 20°C
Ignition Temperature (°C) 440
Flash Point (°C) -10
Lower explosivity limit (LEL) (volume %) 5.6
Upper explosivity limit (UEL) (volume %) 16

Behaviour at sea

Additional data

Colour colourless
Odour unpleasant odour

Transportation data

Transport mode Bulk,Gas,Packaged
Cargo group 35
State liquid
Temperature (°C) ambient
Pressure (Pa) under pressure
Family name vinyl halides
IMO class 3.1

Reactivity data

Water No
Acid(s) Yes
Base(s) No
Metal(s) and alloys No
Oxidizing agents Yes
Reducing agents No
Combustibles No
Organic substance No

GESAMP Hazard profile

Bioaccumulation in logPow (A1A) 2 - ≥2 and <3
Bioaccumulation in BCF (A1B) 1 - ≥1 and <10
Bioaccumulation (A1) 1 - Very low potential to bioaccumulate
Biodegradation (A2) NR - Not readily biodegradable
Acute aquatic toxicity (B1) (LC/EC/IC50 (mg/l)) 2 - Slightly toxic
Acute mammalian toxicity by swallowing (C1) (LD50 (mg/kg)) 2 - Moderate
Acute mammalian toxicity by skin penetration (C2) (LD50 (mg/kg)) 0 - Negligible
Acute mammalian toxicity by inhalation (C3) (LC50 (mg/l)) 2 - Moderate
Eye irritation/corrosivity (D2) 2 - Irritating
Interference with coastal amenities (E2) SD - Sinker/Dissolver
Effects on wildlife and bottom habitats (E3) 3 - Is highly acutely toxic; and/or is severely irritant or corrosive to skin or eyes; and/or is carcinogenic, mutagenic or reprotoxic; and/or is a floater or persistent floater with associated health effects

Human toxicity threshold

TLV-TWA 10
ERPG-2 (ppm) 500
ERPG-3 (ppm) 1000

Ecotoxicity

Incident reports

Incident reports

No incident reports available

Emergency Response Guidebook

Emergency Response Guidebook

Guide number: 130P

See the guide or download the emergency response guidebook

At sea emergency guide

At sea emergency guide

Emergency schedule: 3-02

• 1 CLASS 3.1
FLAMMABLE LIQUIDS, FLASHPOINT BELOW -18 °C Closed Cup., TOXIC AND/OR CORROSIVE; MISCIBLE WITH WATER*
• 2 CLASS 3.2
FLAMMABLE LIQUIDS, FLASHPOINT FROM -18°C TO +23°C Closed Cup., TOXIC AND/OR CORROSIVE; MISCIBLE WITH WATER*
• 3 CLASS 3.3
FLAMMABLE LIQUIDS, FLASHPOINT FROM 23°C TO 61°C Closed Cup., TOXIC AND/OR CORROSIVE; MISCIBLE WITH WATER*

* Includes substances which are partially miscible with water and substances immiscible but reacting with water for which the use of foam may be ineffective.

Emergency procedures

Action

Avoid all sources of ignition (e.g. naked lights, unprotected light bulbs, electric handtools).
Turn ship off-wind.

Spillage on deck

Wash spillage overboard with copious quantities of water.

Spillage under deck

Provide adequate ventilation. Collect spillage, where practicable, using absorbent material, for safe disposal.

Fire on deck

Use water spray or dry chemical. Do NOT use water jet or foam.
If possible remove receptacles likely to be involved or keep them cool with copious quantities of water.

Fire under deck

Batten down; use ship's fixed fire-fighting installation. Otherwise adopt action as for "On deck".

Special equipment to be carried

Protective clothing (gloves, boots, coveralls, headgear).
Self-contained breathing apparatus.
Spray nozzles.

Remarks by UN no.

• HYDRAZINE, ANHYDROUS (UN No. 2029)
Possible self-ignition at ambient temperatures.

Decision trees

Decision trees

No decision trees available

No additional data

last modified 2020-12-14T09:03:03+00:00